空气细颗粒物(PM2.5)污染特征及其毒性机制的研究进展

细颗粒物(PM2.5)是指空气动力学直径≤2.5μm的颗粒物,其表面吸附大量的有毒有害物质,并可通过呼吸沉积在肺泡,甚至可通过肺换气到达其他器官.由于细颗粒物的重要性,美国EPA已经于1997年颁布了细颗粒物的空气质量标准,年均值为0.015mg/m3,日均值为0.065mg/m3,然而我国至今仍未制定细颗粒物空气质量标准.颗粒物上吸附的化学组分主要可分成自然来源及燃煤或燃油等人为污染来源两大类,特别是来自工业性和居住区燃煤及汽车燃油尾气.空气细颗粒物污染表现为形态各异、成分复杂等特征.细颗粒物有明显的毒性作用,可引起机体呼吸系统、免疫系统等较为广泛的损害.细颗粒物与心肺疾病密切相关,如增加入院率、急诊次数、呼吸疾病及症状增加、肺功能下降,甚至于过早死亡.简要概述了细颗粒物的污染特征及其毒性机制研究进展.     

linking various aspects of atmospheric change through a systems analysis of food

Although interdisciplinary collaboration to address a singleenvironmental problem is more common than in the past, all toooften the significant atmospheric problems of our day such asstratospheric ozone depletion, acidic deposition or climaticchange are addressed on a single issue basis. Systems analysis isa way of looking at a problem in a holistic, integrated fashionthrough including as many as practicable of the importantcomponents, and the linkages among them. Systems analysisoften begins with a conceptual model which, even if lackingquantification, is a useful means of changing ones thinking to amulti-issue approach. If possible, conceptual models areoperationalized by quantification (using the best availablescientific knowledge) of the stocks and flows of the relevantcomponents of the problem, and the processes that are involved.In this paper, a systems approach to food production is used tolink various atmospheric issues such as regional acidification andclimatic change. A spreadsheet model of food demand andproduction in various world regions examined the possible effectof atmospheric change on how much food we can grow, andwhether or not we may be able to meet the increased demand inthe year 2025. Using relatively modest changes in factors ofagricultural production, the spreadsheet model calculated globalshortfalls by the year 2025 of the order of 10 to 20% in someimportant agricultural crops, despite the improvements in cropproduction factors that are envisaged by the Food andAgricultural Organization from now until the year 2010, and thatwere extrapolated in this paper to 2025. The model alsocalculated that climatic change in combination with eithertropospheric ozone or increased UV-B radiation caused bydepletion of the stratospheric ozone layer may in general makethe situation worse than in the case of climatic change alone.Given the large uncertainties in the input data, the results in thispaper should not be viewed as predictions but rather as anexample of taking a relatively simple systems approach to foodproduction using a spreadsheet model, and calculating the effectsthat various aspects of atmospheric change might have upon it.Therefore, it is extremely important to know the effects uponcrop production factors of climatic change, tropospheric ozoneand increased UV-B radiation not only as individual issues, butalso of their combined effect since it is probable that in manyregions they will occur in combination.     

乌鲁木齐冬季大气混浊度系数与光气候

本文利用30年的气候资料分析了乌鲁木齐冬季光气候与大气混浊度之间的关系,指出了大气混浊度的增加是造成辐射总照度下降的主要原因.     

Application of CFD Methods for Modelling in Air Pollution Problems: Possibilities and Gaps

Different urban air pollution problems deal with complex structure of air flows and turbulence. For such problems the Computer Fluid Dynamics (CFD) methods become widely used. However, this approach despite a number of advantages has some problems. Experience of use of CFD tools for development of models and suggestions of their applications for a local scale air pollution over a complex terrain and stable stratification are discussed in this paper, including: Topography and complex geometry: choose of the co-ordinate system and computer grid; Turbulence closure for air pollution modelling: modified k- model for stable stratified ABL; Boundary conditions for vertical profiles of velocity for stable-stratified atmosphere; Effects of the radiation and thermal budget of inclined surfaces to dispersion of pollutants; Artificial sources of air dynamics and circulation.Some examples of CFD applications for air pollution modelling for a flat terrain, mountainous area, mining open cast and indoor ventilation are discussed. Modified k- model for stably-stratified ABL is suggested. Due to the isotropic character of the k- model a combination of it in vertical with the sub-grid turbulence closure in horizontal can be more suitable for ABL. An effective scheme of boundary conditions for velocity profiles, based on the developed similarity theory for stable-stratified ABL, is suggested. Alongside with the common studies of atmospheric dispersion, the CFD methods have also demonstrated a good potential for studying anthropogenic and artificial-ventilation sources of air dynamic and circulation in local-scale processes of air pollution.     

中国对流层二氧化硫光化学氧化过程的数值研究

利用一个三维非静力区域大气化学输送模式与中尺度气象模式MM5相连接构成一个数值模拟系统，模拟了中国地区对流层臭氧与其前体物的分布以及二氧化硫转化为硫酸盐的过程，模式扬地面源排放、大气输送和扩散、干沉积、气相化学反应和云雨过程。结果表明：日间，O3浓度主要由NOx和NMHC的源排放和光化学反应过程支配，大气辐射是光化学反应强弱的决定因子，其强度可使SO2、O3和SO4^2-的生成浓度呈现不同的日变化和季节变化，结果表明高浓度的O3对二氧化硫转化为硫酸盐的化学过程有很大的促进作用，然而，这种作用受NMHC浓度的影响很大，较高浓度的NMHC使O3浓度上升，但同时增加了对OH等自由基的消耗，使SO2的转化率降低。     

Observation of atmospheric nitrous acid with DOAS in Beijing, China

Measurements of nitrous acid （HONO） and nitrogen dioxide （NO2） in Beijing City have been performed by means of a developed differential optical absorption spectroscopy （DOAS） system based on photodiode array （PDA）, during the autumn of 2004. HONO and NO2 were simultaneously identified by their characteristic absorption bands in the spectral region between 337 nm and 372 nm with high sensibility and time resolution. The concentrations of HONO exhibit obviously diurnal variation with a nocturnal maximum and a daytime minimum. The highest HONO value up to 11.8 μg/m^3 was observed during the night of 2/3 September. Possible sources of the observed HONO were discussed. Good correlation to NO2 indicates that NO2 is a main source component. The measurement also shows direct emission of HONO is an imnortant source in strongly polluted urban area.     

对熏烟扩散模式应用的探讨

工程上应用的大气污染物扩散模式中 ,熏烟模式由于其非定常性而与其他扩散模式有很大的区别。正确处理模式中各参数及变量的相互关系才能客观地反映污染物对环境影响的结果。本研究通过对熏烟模式的非定常性和各参数、变量相互关系的分析 ,提出了正确使用该模式的方法     

太原市工业区大气中TSP浓度及元素成分分析

采用校正空白称量法对太原市工业区大气中ＴＳＰ浓度进行了测定分析，对该区大气ＴＳＰ浓度随时间变化的规律，超标情况及污染特征进行了研究，同时测定了ＴＳＰ中Ｃｒ、Ｐｂ等１２种元素的含量。     

Effects of atmospheric mercury pollution on terrestrial ecosystem in Chongqing, China

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中国PM_(2.5)污染状况和污染特征的研究

近１０ 余年来在中国的城市地区和清洁地区进行了ＰＭ２－５ 的采集和分析，其中包括ＰＭ２－５ 的质量浓度、离子和元素成分、酸度和酸化缓冲能力以及来源解析，研究结果表明，中国大部分地区ＰＭ２－５ 的污染较重，不论是质量浓度，还是各种主要成分浓度，在ＴＳＰ 和ＰＭ１０ 中都占有很高的比重，而ＰＭ２－５ 的酸度也远远高于ＴＳＰ 和ＰＭ１０ ，特别是近年来ＰＭ２－５ 污染还有相对加剧的趋势。